╨╧рб▒с>■  TV■   S                                                                                                                                                                                                                                                                                                                                                                                                                                                ье┴7 Ё┐°2bjbjUU "d7|7|°.      l$тттт ю<$╢66666666ВДДДДДД$╣ ┘fи66666и╛66╜╛╛╛6F66В╛6В╛а╛^^6* Р8═ fM└$╛т|B^^$╙0^?╛?^╛$$┘Supporting Information Included are details, illustrations and descriptions of the X-ray crystallographic data for compounds 5c (with 6c) and 7c. Compound 5c The X-ray crystallographic analysis was performed on a mixture of 5c and 6c (85.5%:14.5% respectively). The enclosed illustration depicts both structures. The data is included elsewhere in .CIF format and below in .PDB format. CRYST1 6.150 10.433 14.725 74.73 87.33 86.80 SCALE1 0.162602 -0.009091 -0.005393 0.000000 SCALE2 0.000000 0.095999 -0.026004 0.000000 SCALE3 0.000000 0.000000 0.070436 0.000000 ATOM 1 N1 0 3.898 7.522 0.125 1.000 2.41 ANISOU 1 N1 0 209 488 218 55 12 -38 ATOM 2 S1 0 2.627 7.678 1.129 1.000 1.81 ANISOU 2 S1 0 202 231 256 22 32 -24 ATOM 3 CL1 0 8.444 9.562 -4.253 1.000 3.42 ANISOU 3 CL1 0 370 556 372 -79 61 93 ATOM 4 O1 0 2.042 6.426 1.521 1.000 2.73 ANISOU 4 O1 0 372 258 407 -50 63 -4 ATOM 5 O2 0 1.733 8.667 0.593 1.000 2.52 ANISOU 5 O2 0 299 286 373 71 -29 -23 ATOM 6 C1 0 3.679 8.271 2.454 1.000 2.16 ANISOU 6 C1 0 311 264 246 19 -6 -29 ATOM 7 C2 0 3.047 8.251 3.812 1.000 2.58 ANISOU 7 C2 0 410 299 272 85 55 -59 ATOM 8 C3 0 3.628 7.684 4.849 1.000 2.79 ANISOU 8 C3 0 453 369 239 33 74 -38 ATOM 9 C4 0 4.928 6.910 4.759 1.000 2.85 ANISOU 9 C4 0 320 503 259 -14 9 59 ATOM 10 C5 A 0 5.092 6.349 3.306 0.855 2.01 ANISOU 10 C5 A 0 247 297 220 22 26 4 ATOM 11 C6 A 0 4.984 7.467 2.271 0.855 1.94 ANISOU 11 C6 A 0 232 294 210 -37 11 38 ATOM 12 C5AB 0 5.651 7.195 3.506 0.145 2.43 ANISOU 12 C5AB 0 329 345 251 -71 -11 19 ATOM 13 C6AB 0 4.629 6.910 2.518 0.145 1.70 ANISOU 13 C6AB 0 348 157 142 43 203 50 ATOM 14 C7 0 5.017 6.896 0.846 1.000 2.22 ANISOU 14 C7 0 198 391 254 25 15 -10 ATOM 15 C8 0 3.710 7.272 -1.305 1.000 2.21 ANISOU 15 C8 0 261 350 229 -4 -11 -51 ATOM 16 C9 0 4.872 7.858 -2.073 1.000 1.99 ANISOU 16 C9 0 271 268 216 42 -21 -19 ATOM 17 C10 0 5.450 7.162 -3.124 1.000 2.61 ANISOU 17 C10 0 352 319 322 -31 17 -117 ATOM 18 C11 0 6.532 7.688 -3.820 1.000 2.90 ANISOU 18 C11 0 381 426 294 -8 82 -116 ATOM 19 C12 0 7.037 8.911 -3.439 1.000 2.37 ANISOU 19 C12 0 292 348 259 18 6 67 ATOM 20 C13 0 6.482 9.627 -2.398 1.000 2.60 ANISOU 20 C13 0 404 215 370 -22 24 -5 ATOM 21 C14 0 5.398 9.097 -1.728 1.000 2.56 ANISOU 21 C14 0 419 250 302 44 52 -59 ATOM 22 C15 0 4.998 5.758 5.728 1.000 2.36 ANISOU 22 C15 0 328 390 177 25 23 -42 ATOM 23 C16 0 6.171 5.492 6.431 1.000 2.83 ANISOU 23 C16 0 311 493 272 46 0 -78 ATOM 24 C17 0 6.245 4.401 7.289 1.000 3.59 ANISOU 24 C17 0 478 558 327 211 -43 -22 ATOM 25 C18 0 5.162 3.570 7.460 1.000 3.91 ANISOU 25 C18 0 683 426 375 180 105 55 ATOM 26 C19 0 4.002 3.811 6.763 1.000 3.46 ANISOU 26 C19 0 513 378 425 2 176 -20 ATOM 27 C20 0 3.917 4.901 5.903 1.000 2.85 ANISOU 27 C20 0 319 469 295 15 43 -65 Compound 7c In the X-ray crystallographic analysis of 7c there were two independent molecules per asymmetric unit. These are the two enantiomers of 7c. The enclosed illustration depicts both structures. The data is included elsewhere in .CIF format and below in .PDB format. CRYST1 12.398 9.766 16.128 90.00 95.65 90.00 SCALE1 0.080661 0.000000 0.007986 0.000000 SCALE2 0.000000 0.102394 0.000000 0.000000 SCALE3 0.000000 0.000000 0.062309 0.000000 ATOM 1 S1 0 -0.022 -2.768 -3.328 1.000 2.45 ANISOU 1 S1 0 273 379 281 6 40 2 ATOM 2 CL1 0 -5.006 2.059 1.300 1.000 4.10 ANISOU 2 CL1 0 551 586 422 110 120 -132 ATOM 3 O1 0 1.179 -3.155 -2.641 1.000 3.32 ANISOU 3 O1 0 341 533 386 42 -32 -12 ATOM 4 N1 0 -1.036 -2.114 -2.210 1.000 2.46 ANISOU 4 N1 0 297 378 261 48 11 -40 ATOM 5 C1 0 -0.873 -4.253 -3.892 1.000 2.60 ANISOU 5 C1 0 342 400 246 51 -11 -59 ATOM 6 O2 0 0.060 -1.861 -4.429 1.000 3.15 ANISOU 6 O2 0 362 463 370 13 102 68 ATOM 7 C2 0 0.061 -5.014 -4.807 1.000 3.22 ANISOU 7 C2 0 525 463 234 68 22 -8 ATOM 8 C3 0 0.572 -6.190 -4.488 1.000 3.14 ANISOU 8 C3 0 438 473 282 70 -9 -108 ATOM 9 C4 0 0.314 -6.912 -3.182 1.000 2.91 ANISOU 9 C4 0 369 325 409 -5 -9 15 ATOM 10 C5 0 -0.282 -5.966 -2.134 1.000 2.92 ANISOU 10 C5 0 407 391 312 -22 62 10 ATOM 11 C6 0 -1.417 -5.122 -2.731 1.000 2.79 ANISOU 11 C6 0 318 374 369 -19 -3 -10 ATOM 12 C7 0 -2.163 -4.288 -1.677 1.000 3.12 ANISOU 12 C7 0 404 456 327 29 119 62 ATOM 13 C8 0 -1.384 -3.089 -1.136 1.000 2.86 ANISOU 13 C8 0 404 422 261 94 37 -5 ATOM 14 C9 0 -2.186 -1.350 -2.781 1.000 2.69 ANISOU 14 C9 0 323 406 291 39 15 -28 ATOM 15 C10 0 -2.875 -0.530 -1.721 1.000 2.44 ANISOU 15 C10 0 329 371 230 61 -17 20 ATOM 16 C11 0 -2.187 0.480 -1.046 1.000 2.82 ANISOU 16 C11 0 318 425 329 10 12 -41 ATOM 17 C12 0 -2.832 1.291 -0.118 1.000 2.94 ANISOU 17 C12 0 387 436 294 -51 11 -67 ATOM 18 C13 0 -4.164 1.049 0.136 1.000 2.73 ANISOU 18 C13 0 403 392 242 91 35 -9 ATOM 19 C14 0 -4.868 0.037 -0.484 1.000 3.00 ANISOU 19 C14 0 287 519 333 -25 24 -8 ATOM 20 C15 0 -4.202 -0.754 -1.419 1.000 2.94 ANISOU 20 C15 0 340 397 378 -40 10 -45 ATOM 21 C16 0 1.633 -8.965 -2.568 1.000 3.43 ANISOU 21 C16 0 421 464 419 29 49 -13 ATOM 22 C17 0 2.766 -9.600 -2.125 1.000 4.17 ANISOU 22 C17 0 579 491 514 132 6 98 ATOM 23 C18 0 3.894 -8.857 -1.807 1.000 4.81 ANISOU 23 C18 0 456 926 445 152 -12 70 ATOM 24 C19 0 3.842 -7.489 -1.885 1.000 4.36 ANISOU 24 C19 0 375 906 376 -70 43 25 ATOM 25 C20 0 2.705 -6.839 -2.338 1.000 3.32 ANISOU 25 C20 0 418 463 380 -53 112 23 ATOM 26 C21 0 1.574 -7.596 -2.695 1.000 2.81 ANISOU 26 C21 0 353 440 274 -5 29 -41 ATOM 27 S1' 0 -7.052 0.921 4.723 1.000 2.54 ANISOU 27 S1' 0 325 385 257 23 20 9 ATOM 28 CL1' 0 -1.950 6.649 8.076 1.000 3.93 ANISOU 28 CL1' 0 588 486 417 -83 -14 -52 ATOM 29 O2' 0 -7.377 1.836 3.670 1.000 3.20 ANISOU 29 O2' 0 449 431 334 70 -17 34 ATOM 30 O1' 0 -8.106 0.447 5.571 1.000 3.54 ANISOU 30 O1' 0 389 604 352 -44 109 -12 ATOM 31 N1' 0 -5.918 1.624 5.691 1.000 2.91 ANISOU 31 N1' 0 383 452 270 -30 15 8 ATOM 32 C1' 0 -6.187 -0.483 3.994 1.000 2.86 ANISOU 32 C1' 0 363 426 299 30 49 -38 ATOM 33 C2' 0 -7.150 -1.277 3.151 1.000 2.77 ANISOU 33 C2' 0 415 423 216 49 -18 -28 ATOM 34 C3' 0 -7.568 -2.465 3.488 1.000 3.23 ANISOU 34 C3' 0 419 445 365 -3 27 -81 ATOM 35 C4' 0 -7.218 -3.181 4.776 1.000 3.50 ANISOU 35 C4' 0 465 393 473 55 -19 40 ATOM 36 C5' 0 -6.474 -2.251 5.764 1.000 3.60 ANISOU 36 C5' 0 474 500 392 6 -83 32 ATOM 37 C6' 0 -5.478 -1.344 5.056 1.000 3.21 ANISOU 37 C6' 0 392 442 387 76 16 45 ATOM 38 C7' 0 -4.606 -0.499 6.009 1.000 3.62 ANISOU 38 C7' 0 404 529 443 31 -82 41 ATOM 39 C8' 0 -5.361 0.666 6.669 1.000 3.39 ANISOU 39 C8' 0 509 490 290 1 -81 4 ATOM 40 C9' 0 -4.913 2.445 4.959 1.000 3.43 ANISOU 40 C9' 0 462 490 351 -76 68 -58 ATOM 41 C10 0 -4.194 3.416 5.864 1.000 2.71 ANISOU 41 C10 0 321 398 310 37 67 11 ATOM 42 C11 0 -2.912 3.800 5.480 1.000 3.84 ANISOU 42 C11 0 459 621 380 -27 143 -148 ATOM 43 C12 0 -2.227 4.772 6.164 1.000 3.89 ANISOU 43 C12 0 326 713 437 -44 114 -120 ATOM 44 C13 0 -2.815 5.382 7.242 1.000 2.97 ANISOU 44 C13 0 406 447 274 -4 -25 25 ATOM 45 C14 0 -4.082 5.002 7.674 1.000 3.19 ANISOU 45 C14 0 473 452 287 59 105 -48 ATOM 46 C15 0 -4.770 4.030 6.976 1.000 3.13 ANISOU 46 C15 0 348 505 337 1 102 -56 ATOM 47 C16 0 -9.541 -2.989 5.720 1.000 3.92 ANISOU 47 C16 0 513 477 502 -14 -69 134 ATOM 48 C17 0 -10.673 -3.522 6.326 1.000 4.30 ANISOU 48 C17 0 431 708 495 7 -86 150 ATOM 49 C18 0 -10.711 -4.886 6.597 1.000 4.06 ANISOU 49 C18 0 516 641 385 -167 -100 102 ATOM 50 C19 0 -9.652 -5.691 6.288 1.000 3.93 ANISOU 50 C19 0 663 445 385 -109 -95 35 ATOM 51 C20 0 -8.513 -5.153 5.694 1.000 3.52 ANISOU 51 C20 0 576 421 342 -16 -102 -24 ATOM 52 C21 0 -8.441 -3.797 5.408 1.000 3.27 ANISOU 52 C21 0 446 409 386 -6 -76 20 ~АЗЙЛПФабфчыэЖЗ/1ОРў2°2¤¤√¤ўўў√ўўў√5Б\Б\Б5БУФбвЖЗ╛Ў.fйЁ3z╜GО╤ [ в х , ·Єъъшууъсссссссссссссссссс$a$$dha$$dha$dh°2¤, o ╢ ∙ @ Г ╩ T Ч ▐ ! 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